Study of fluorine contamination on MgO(100) surfaces
✍ Scribed by I Colera; E Soria; J.L de Segovia; R González
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 319 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0042-207X
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✦ Synopsis
The ¯uorine contamination on MgO(100) surfaces is studied using Electron Stimulated Desorption (ESD) and Auger Electron Spectroscopy (AES). While Ar + ion sputtering is very eective to clean the carbon contamination on the surface, the ¯uorine content does not signi®cantly decrease. Thermal treatments of the sample considerably increase the F surface concentration due to its diusion from the bulk to the surface. Heating the sample at 700 K simultaneously with H 2 O exposure produces a decrease in the ¯uorine signal. The ion kinetic energy distribution of the F + ion shows two peaks at 2.4 and 5 eV. The threshold energy of the F + ion desorption is at 60 eV.
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Ab initio and semiempirical calculations have been performed on an ## Ž . Ž . MgO cluster model in order to study the effects of water coverage on pure MgO 100 16 surfaces. The geometries of various adsorbed water molecules have been optimized and the binding energies, charge transfer, and prefer