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Study of equilibrium in the presence of an intramolecular donor-acceptor interaction in ω-dialkylaminoalkylboron compounds by the NMR method

✍ Scribed by B. M. Mikhailov; V. S. Bogdanov; L. S. Vasil'ev; V. A. Dorokhov; V. P. Dmitrikov; V. G. Kiselev; A. D. Naumov

Book ID
112422220
Publisher
Springer
Year
1970
Tongue
English
Weight
67 KB
Volume
19
Category
Article
ISSN
1573-9171

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Application of NMR spectroscopy of chiral association complexes. 12—rate determination of an intramolecular motion in a free molecule by means of dynamic NMR measurements in the presence of an auxiliary compound
✍ Reinhard Küspert; Albrecht Mannschreck 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 523 KB

## Abstract The rate constants of intramolecular processes can sometimes be measured only in the presence of optically active auxiliary compounds. The problem of obtaining the rate for the free molecule was solved by linear extrapolation of rate constant from the complexed to the uncomplexed molecu