Study of cloverite molecular sieves modified by grafting organometallic complexes inside the pores: II. Adsorption properties of cloverite modified by grafting –SnR3 fragments (R=Me, Et, nBu, Cy)

Study of cloverite molecular sieves modi

Study of cloverite molecular sieves modified by grafting organometallic complexes inside the pores: I. Synthesis and characterization of cloverite modified by grafting –SnR3 fragments (R=Me, Et, n-Bu, Cy)

✍ M. Adachi; J. Corker; H. Kessler; F. Lefebvre; J.M. Basset 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 285 KB

The reaction of various alkyltin compounds [HSnBu 3 and SnR 4 , R=Me, Et, cyclohexyl (Cy)] with cloverite dehydroxylated at 450°C was studied by various methods such as 1H, 31P and 119Sn MAS NMR, 13C CP-MAS NMR, infrared spectroscopy, analysis of evolved gases, thermolysis and chemical analysis. All