Study of Bis [N, N1-Dicyclopropyldithiooxamidato (-1)-S,S'] Palladium(II) by X Ray Diffraction, UV-VIS and IR Spectroscopy
✍ Scribed by H. Hofmans; H. O. Desseyn; A. T. H. Lenstra
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 351 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0037-9646
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## Abstract The gas‐phase structure of __N,S,S__‐trimethylsulfoximine 1 and of its monolithiated isomers 2–4 was calculated by __ab initio__ methods. It was found that a LiCSN four‐membered chelate 2 is the most stable isomer. The second minimum 4 shows NLiO complexation and is only slightly h
## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_