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Study in Terpene Series. XI. 1 The Dehydroxymethylation of Bicyclic Primary Terpenic Alcohols by Hydrogenolysis in the Presence of Nickel Catalysts 2

✍ Scribed by Ipatieff, V. N.; Czajkowski, G. J.; Pines, Herman

Book ID: 126959391
Publisher: American Chemical Society
Year: 1951
Tongue: English
Weight: 531 KB
Volume: 73
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01153a014

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✍ Pines, Herman; Olberg, R. C.; Ipatieff, V. N. 📂 Article 📅 1952 🏛 American Chemical Society 🌐 English ⚖ 571 KB

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An example of the valorization of terpen

An example of the valorization of terpenes: The selective isomerization of 3-carene to 2-carene in the presence of silica supported nickel catalysts modified by tetrabutyl tin

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The cyclic olefin, 3-carene, undergoes an isomerization of the carbon-carbon double bond to produce 2-carene, a precursor in the synthesis of ( -)-menthol. This isomerization is observed over silica supported nickel, but the selectivity is reduced by side reactions producing trimethylheptenes by hyd