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Study Concerning the Effects of Chelation on the Structure and Catalytic Activity of Ruthenium Carbene Complexes

✍ Scribed by Fürstner, Alois; Thiel, Oliver R.; Lehmann, Christian W.

Book ID
115498269
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
79 KB
Volume
21
Category
Article
ISSN
0276-7333

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## Abstract Structural modifications of the Hoveyda–Grubbs ruthenium metathesis complex __via__ electronic and structural withdrawing of the chelating alkoxy ligand were investigated. By decreasing the donor properties of the oxygen atom, an acceleration in catalytic activity was achieved based on