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Studies with radioactive sugars : Part IV. The Methanolysis of D-fructose and L-sorbose

โœ Scribed by G.S. Bethell; R.J. Ferrier


Book ID
108308122
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
789 KB
Volume
31
Category
Article
ISSN
0008-6215

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The formation of dinuclear tungstate and molybdate complexes of D-fructose and L-sorbose was studied in aqueous solution by I H, ~3C, and ~83W NMR spectroscopy. These ketoses react only in acyclic forms, because HO-3,4 are trans in the cyclic lbrms. With tungstate, both sugars form a major complex o