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Studies Towards the Total Synthesis of Novel Dolabellane-Type Diterpenoids: Construction of the 5,11-Fused Bicyclic Framework.

✍ Scribed by Goverdhan Mehta; Jayant D. Umarye


Publisher
John Wiley and Sons
Year
2003
Weight
116 KB
Volume
34
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Studies towards the total synthesis of n
✍ Goverdhan Mehta; Jayant D. Umarye πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 137 KB

An oxy-Cope protocol has been grafted on to a previously crafted hydroazulenic system to provide a facile entry into the 5,11-fused bicyclic skeleton present in the novel neodolabellane diterpenoids. Formation of a novel tricyclic diterpenoid framework, generated through a transannular cyclization i

Studies towards the total synthesis of n
✍ Goverdhan Mehta; R.Senthil Kumaran πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 73 KB

The synthesis of the tetracyclic core present in the novel marine diterpenoid havellockate 1 has been accomplished from the readily available endo-dicyclopentadienone-10-ethylene ketal 3 as a prelude to the projected total synthesis of the natural product.