Studies towards diarylheptanoid synthesis. Part 2: Synthesis and ring cleavage reactions of tetrahydro-4H-furo[2,3-b]pyran-2-ones
โ Scribed by Sidika Polat Cakir; Keith T. Mead; Laura T. Smith
- Book ID
- 104254058
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 415 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Lewis acid promoted anomeric substitution reactions of a stereoselectively prepared hexahydro-2H,5H-pyrano[2,3b]pyran-2-one derivative was studied as a model for diarylheptanoid synthesis. Aromatic nucleophiles consistently provided the expected thermodynamic C-aryl pyranoside product.
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract Furo[3,2โ__c__]pyranโ4โones, which possess a naturalโproduct skeleton, are synthesized __via__ a simple, oneโpot, threeโcomponent reaction of furanโ2,3โdiones with dialkyl acetylenedicarboxylates and Ph~3~P.