Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 wit
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Adams, Richard D. ;Barnard, Thomas S. ;Li, Zhaoyang ;Zhang, Lijuan
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Article
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1997
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Wiley (John Wiley & Sons)
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English
⚖ 497 KB
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The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d