𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies on vitamin D and related compounds XIV Investigations on sterols XVII: The photoisomerization of pre-ergocalciferol and tachysterol2

✍ Scribed by M. P. Rappoldt


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
389 KB
Volume
79
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The quantum yields of the isomerizations of pre‐ergocalciferol and tachysterol~2~ in ether at 20Β° under the influence of ultraviolet light of 2537 Γ… were found to be 0.49 and 0.11 respectively. Ergosterol is not formed from tachysterol~2~ during irradiation but originates exclusively from pre‐ergocalciferol. The origin of lumisterol~2~ is somewhat less certain; it seems to be formed from tachysterol~2~.


πŸ“œ SIMILAR VOLUMES


Investigations on sterols XIV studies on
✍ M. P. Rappoldt πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 328 KB

## Abstract Kinetic experiments on the isomerization of lumisterol~2~ under the influence of ultraviolet light of various wavelengths are reported. The experiments indicate that neither tachysterol~2~ nor ergosterol are primary reaction products of lumisterol~2~. Lumisterol~2~ is exclusively conver

Studies on vitamin D and related compoun
✍ J. Lugtenburg; E. Havinga πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 163 KB

Although many stereochemical features of vitamin D and its ieomeric precursor6 may be coneidered rather well established (1,2) by now, there remain a few intriguing questions. One of the problems that asked for further study, is concerned with the conformational analysis of tachyeterol (Fig. I). The

Studies on vitamin D and related compoun
✍ A. Verloop; A. L. Koevoet; R. van Moorselaar; E. Havinga πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 393 KB

## Abstract Details on the iodine‐catalyzed reactions of previtamin D, tachysterol, __cis‐__ and __trans__‐vitamin D (influence of solvent, concentration, wavelength of light) are given. The possibility of a previtamin D determination based on the __cis/trans__ isomerisation is indicated. Some resu