## Abstract Kinetic experiments on the isomerization of lumisterol~2~ under the influence of ultraviolet light of various wavelengths are reported. The experiments indicate that neither tachysterol~2~ nor ergosterol are primary reaction products of lumisterol~2~. Lumisterol~2~ is exclusively conver
Studies on vitamin D and related compounds XIV Investigations on sterols XVII: The photoisomerization of pre-ergocalciferol and tachysterol2
β Scribed by M. P. Rappoldt
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 389 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0165-0513
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β¦ Synopsis
Abstract
The quantum yields of the isomerizations of preβergocalciferol and tachysterol~2~ in ether at 20Β° under the influence of ultraviolet light of 2537 Γ were found to be 0.49 and 0.11 respectively. Ergosterol is not formed from tachysterol~2~ during irradiation but originates exclusively from preβergocalciferol. The origin of lumisterol~2~ is somewhat less certain; it seems to be formed from tachysterol~2~.
π SIMILAR VOLUMES
Although many stereochemical features of vitamin D and its ieomeric precursor6 may be coneidered rather well established (1,2) by now, there remain a few intriguing questions. One of the problems that asked for further study, is concerned with the conformational analysis of tachyeterol (Fig. I). The
## Abstract Details on the iodineβcatalyzed reactions of previtamin D, tachysterol, __cisβ__ and __trans__βvitamin D (influence of solvent, concentration, wavelength of light) are given. The possibility of a previtamin D determination based on the __cis/trans__ isomerisation is indicated. Some resu