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Studies on the total synthesis of triptolide. II. the C-ring functionality of triptonide.

✍ Scribed by Donna M. Frieze; Glenn A. Berchtold; John F. Blount

Book ID
104237332
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
188 KB
Volume
19
Category
Article
ISSN
0040-4039

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✍ Duy H. Hua; S. Venkataraman πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 262 KB

A stereoselective construction of the C-ring fragment of trichothecenes from readily available 4-cumyloxy-2-cyclopentenol in 12 steps (24% overall yield) is described. We have recently described an asymmetric synthesis based on the reaction of enones with chiral sulfinylallyl anions.' The utilizatio