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Studies on the Thermal Ring-Opening Reactions of cis -3,4-Bis(organosilyl)cyclobutenes

✍ Scribed by Hasegawa, Munehiro; Murakami, Masahiro


Book ID
127096539
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
205 KB
Volume
72
Category
Article
ISSN
0022-3263

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The thermally induced ring opening of 1 and 5 proceeds with found, a behaviour that corresponds with the known photochemistry of cyclobutenes. A surprising reaction was high stereospecifity in a conrotatory fashion in agreement with the Woodward-Hoffmann rules. Upon flash pyrolysis of found if 1 and