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Studies on the synthesis of side-chain hydroxylated metabolites of vitamin D. 2. Stereocontrolled synthesis of 25-hydroxyvitamin D2

✍ Scribed by Sardina, F. Javier; Mourino, Antonio; Castedo, Luis

Book ID
127191233
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
939 KB
Volume
51
Category
Article
ISSN
0022-3263

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Studies on the synthesis of side chain hydroxylated metabolites of vitamin D. Stereospecific syntheses of 25-hydroxy-7,8-dihydroergosterol and its C-24 epimer
✍ F.J. Sardina; A. MouriΓ±o; L. Castedo πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 214 KB

An efficient, stereospecific synthesis of 25-hydroxy-7,8-dihydroerqosterol, starting from the aldehyde 3 (7 steps, 30,: overally was developed. Key steps are the stereospecific displacement of an allylic carbamate by