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Studies on the stereospecificity of hydrogen transfer by NAD(P) analogues

โœ Scribed by W. Christ; D. Rakow; H. Coper


Book ID
112304238
Publisher
Springer
Year
1976
Tongue
English
Weight
79 KB
Volume
279
Category
Article
ISSN
1618-2650

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Hydride transfer mechanisms of the reductions of xanthylium ion by NAD(P)H analogues (i.e. BNAH, HEH and AcrH 2 ) were investigated. Both the kinetic observations and an analysis of thermodynamic driving forces for each mechanistic step in all the possible mechanisms indicate that the reductions are