Studies on the Stablest Geometries and CP Bonding Nature in P-ylide CH2PH3 and P-ylide-like Radical ·CHPH3

Different Coordination Modes of the Poly

Different Coordination Modes of the Polyfunctional Ylide Ph3P=C(H)C(O)CH2C(O)OEt: C- vs. O,O′-Bonding in PdII, PtII and AuI Complexes

✍ Marta Carbó; Larry R. Falvello; Rafael Navarro; Tatiana Soler; Esteban P. Urriol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB

## Abstract Treatment of the polyfunctional ylide Ph~3~P=C(H)C(O)CH~2~COOEt (1) with the solvated complexes [M(C^∧^X)(THF)~2~]ClO~4~ gave the __O__,__O′__ derivatives [M(C^∧^X)(Ph~3~PCH~2~C(__O__)=C(H)−C(=__O__)OEt‐κ‐__O__,__O′__]ClO~4~ [M(C^∧^X) = Pd(C~6~H~4~CH~2~NMe~2~) (2), Pd(CH~2~C~9~H~6~N) (3