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Studies on the stability of oxygen radical spin adducts of a new spin trap: 5-methyl-5-phenylpyrroline-1-oxide (MPPO)

โœ Scribed by Nagaraju Sankuratri; Yashige Kotake; Edward G. Janzen

Book ID
113386961
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
675 KB
Volume
21
Category
Article
ISSN
0891-5849

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๐Ÿ“œ SIMILAR VOLUMES

Chiral Spin Traps. The Spin Trapping Che
Chiral Spin Traps. The Spin Trapping Chemistry of 5-Methyl-5-phenylpyrroline-N-oxide (MPPO)
โœ Edward G. Janzen; Nagaraju Sankuratri; Yashige Kotake ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 179 KB

The use of 5,5-dimethylpyrroline-N-oxide ( DMPO ) as a veralso efficiently trapped, such as alkoxyl (5), alkylperoxyl satile spin trap was first published in this journal ( E. G. Janzen (6), hydroxyalkyl (7), alkyl (8), thiyl (9), and aryl (10). and J. I.-P. Liu, J. Magn. Reson. 9, 510 -512 ( 1973 )

Synthesis and stereochemistry of the spi
Synthesis and stereochemistry of the spin adducts of a new chiral spin trap, 3,5-diphenyl-5-methylpyrroline-1-oxide
โœ Josphat C. Matasyoh; Ulrich Abram; Paul Schuler; Hartmut B. Stegmann ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 274 KB

The synthesized spin trap 3,5-diphenyl-5-methylpyrroline-1-oxide (3), its derivatives and spin adducts were studied using NMR, ESR and ENDOR spectroscopic methods. The structure of 3 was determined using x-ray analysis. The nitrone 3 was found to have a rigid structure. Two species were observed in