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Studies on the reaction of copper(II) with thiourea—II: The modification of bjerrum's method. The determination of equilibrium in simultaneous redox and complexation reactions

✍ Scribed by Salomea Krzewska; Lech Pajdowski; Halina Podsiadły

Book ID
115975969
Publisher
Elsevier Science
Year
1980
Weight
146 KB
Volume
42
Category
Article
ISSN
0022-1902

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The Reaction of (Bipyridyl)palladium(II)
The Reaction of (Bipyridyl)palladium(II) Complexes with Thiourea − Influence of DNA and Other Polyanions on the Rate of Reaction
✍ Matteo Cusumano; Maria Letizia Di Pietro; Antonino Giannetto; Pasquale Antonio V 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB

## Abstract [Pd(bipy)(py)~2~](PF~6~)~2~ reacts stepwise with excess thiourea to give [Pd(tu)~4~](PF~6~)~2~. The kinetics of the second step, which refers to the replacement of bipyridyl in [Pd(bipy)(tu)~2~](PF~6~)~2~, have been studied in water and in the presence of calf thymus DNA, sodium polyrib