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Studies on the reaction of benzene and other hydrocarbons with aluminium trichloride: Effect of catalytically activated hydrogen

✍ Scribed by Yee-Hing Lai; Linda S. Benner; K.Peter C. Vollhardt

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 933 KB
Volume: 63
Category: Article
ISSN: 0016-2361
DOI: 10.1016/0016-2361(84)90043-7

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✦ Synopsis

A detailed analysis of the volatile hydrocarbons obtained from the reaction of benzene and AICI, was performed. Several experiments point to the intermediacy of phenylcyclohexane as a primary product. 13C-12C exchange was observed using a 1:l mixture of 13C6H6 and '*CsHs. Hydrogenation was predominant when polybenzenoids were reacted with AICI, in the presence of PtO,/H,. Cycloalkanes, however, undergo mainly ring contraction reactions.

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