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Studies on the polymerization of ethyl acrylate. III. Effect of temperature on the solvent-transfer reaction

✍ Scribed by Raghuram, P. V. T. ;Nandi, U. S.

Publisher
Wiley (John Wiley & Sons)
Year
1970
Tongue
English
Weight
373 KB
Volume
8
Category
Article
ISSN
0449-296X

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✦ Synopsis

Abstract

The effect of temperature on transfer constants for different solvents in the polymerization of ethyl acrylate was observed. Activation energy differences (E~trS~ − E~p~) and frequency factors were computed. It is observed that high frequency factors are associated with high activation energies. Values of E~trS~ were calculated by an approximate method and were compared with the available data on methyl methacrylate, isobutyl methacrylate, and styrene.

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