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Studies on the oxidation of enamines with molecular oxygen. I. Oxidation of Some Piperidino Alkenes

โœ Scribed by Karla Blau; Dr. V. Voerckel


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
443 KB
Volume
331
Category
Article
ISSN
1615-4150

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The halogenated Porphyrin, 2,12,13,17,l5,~~hy~nat~iron(III) chloride, [ Fe( TPPPBr,)Cl] , catalyzes the oxidation of cyclohexene in the presence of molecular oxygen or iodosobenzene. With PhIO, 77% epoxide is observed, consistent with a mechanism involving a high-valent metaI-oxo species. With dioxy