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Studies on the Official Method for Pyridine in Ammonium Nitrate.

✍ Scribed by Ladd, R. M.


Book ID
127294707
Publisher
American Chemical Society
Year
1919
Weight
561 KB
Volume
11
Category
Article
ISSN
0095-9014

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The radical cyclization of 3-oxopropanenitriles 1a -1e and alkenes 2a -2g with cerium(IV) ammonium nitrate (CAN) in ether solvents was investigated (Tables 1 and2). In the optimization study, 1,3-dioxolane, 1,4-dioxane, 1,2-dimethoxyethane, Et 2 O, and THF were used as ether-based solvents, and the