Studies on the mechanism of biosynthesis of wax esters inEuchaeta norvegica
โ Scribed by J. R. Sargent; R. McIntosh
- Publisher
- Springer-Verlag
- Year
- 1974
- Tongue
- English
- Weight
- 746 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0025-3162
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โฆ Synopsis
Preparations of Euchaeta norvegica eatalyse the incorporation of (1-14C) hexadecanol, (9,10-~H~) oleie acid, (U-I~C) glucose, (U-I~C) alanine and (U-I~C) aspartie acid into wax esters. Both the fatty alcohol and fatty acid moieties of the wax esters are labelled, indicating de novo biosynthesis. A limited interconversion of fatty acid and fatty alcohol has been demonstrated. Incorporation of glucose into wax esters is diminished by prior starving of E. norvegica; it is also reduced in the presence of ecdysterone. ~ormation of wax esters fl-om glucose is inhibited by increased oxygen tensions, rotenone and dinitrophenol, and is relatively insensitive to decreased oxygen tensions and cyanide. The data are discussed with particular reference to the reasons why wax esters are biosyathesised by calanoids.
๐ SIMILAR VOLUMES
Cations la, E, &, and E are presumed to be the key intermediates in the enzymic cyclization of farnesyl pyrophosphate and the starting points for the intricate series of cyclization and rearrangement steps which lead to a variety of polycyclic sesquiterpenes. 1 Despite considerable speculation, 2 th