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Studies on the kinetics and mechanism of oxygen exchange between solvent water and pentachlorooxomolybdate(2-)

โœ Scribed by Kim, Chang Su; Murmann, R. Kent

Book ID
127069552
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
714 KB
Volume
23
Category
Article
ISSN
0020-1669

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โœ Fred F. Kashani; R. Kent Murmann ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 479 KB ๐Ÿ‘ 1 views

The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex