Studies on the isothermal crystallization kinetics and crystal morphology of PTT/SGF composites

✍ Scribed by Mingtao Run; Yanping Hao; Zhihui He

• Publisher: Society for Plastic Engineers
• Year: 2009
• Tongue: English
• Weight: 596 KB
• Volume: 31
• Category: Article
• ISSN: 0272-8397
• DOI: 10.1002/pc.20884

✦ Synopsis

Abstract

The kinetics of isothermal crystallization and crystal morphology of poly(trimethylene terephthalate)/short glass fibers (PTT/SGF) composites were investigated by using differential scanning calorimetry (DSC) and polarized optical microscopy (POM). DSC data was analyzed by the Avrami equation and Hoffman‐Lauritzen theory. The results show that SGF plays a role as the nucleating agent, which largely accelerates the crystallization rate of PTT. SGF below 20% will increase the crystallinity of the composites but 30% SGF will decrease the crystallinity, which is also verified by the crystallinity results calculated from the wide‐angle x‐ray diffraction (WAXD) experiments. The crystal morphology of the composites exhibits so much microcrystallites because of the fast crystallization rate and the strong interaction between SGF and polymers, which is consistent with the results analysized by the Avrami theory. The nuclei exponent K~g~ is increased sharply as the SGF added into polymer, and SGF makes PTT easier to crystallize during isothermal crystallization process. POLYM. COMPOS., 2010. © 2009 Society of Plastics Engineers