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Studies on the hydrolysis of clavulanic acid

โœ Scribed by Finn, Malcolm J.; Harris, Michael A.; Hunt, Eric; Zomaya, Iskander I.

Book ID
120306056
Publisher
Royal Society of Chemistry
Year
1984
Weight
693 KB
Category
Article
ISSN
1472-7781

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The mechanism of the A2 acid hydrolysis of methyl carbamate was investigated using MNDO method. The reaction was found to proceed in two steps: (1) the rate-determining nucleophilic attack of water on the carbonyl carbon of the N-protonated tautomer involving the tetrahedral TS; and (2) the fast sub