Studies on the formation and decomposition of copper(III) and nickel(III) complexes with macrocyclic ligands containing amide groups
✍ Scribed by Fuping Kou; Shourong Zhu; Huakuan Lin; Keqin Ma; Yunti Chen
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 507 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0277-5387
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Nickel(II) complexes of mono-and bis(macrocyclic) ligands are the products of a nickel(II)-assisted template reaction with 2,3,2-tet, melamine and formaldehyde [2,3,2-tet = bis-N,NЈ-(2-aminoethyl)propane-1,3-diamine; melamine = 2,4,6-triamino-1,3,5-triazine]. The structures of two four-coordinate, d
## Abstract The protonation and deprotonation rates of the coordinated amide group in the Cu~2+~ complexes with N^α^‐(2‐pyridyl‐methyl)‐glycinamide (I) and N^α^‐(2‐pyridyl‐methyl)‐glycineethylamide (II) have been studied by stopped flow techniques. It is shown that the rate determining step of the