Studies on the electrochemical mechanism of reduction of carbonyl compounds
β Scribed by J.P. Stradins
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 645 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0013-4686
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Aryltritylketones ArCOR were reduced in aprotic deoxygenated dimethylformam ide. Product distribution after electrolysis showed the formation of a diester involving the solvent and the formation of ACO' provoked by the seission of the C-C bond of the anion radical. This kind of cleavage is somewhat
A polarographic and kinetic study of the reduction of diacetyl has been carried out in the 0 < pH < 10 range in buffered aqueous solutions. The effect of pH, the diacetyl concentration, the height of the mercury column, the drop time, and temperature on the limiting current is studied. A discussion