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Studies on the disproportionation of trichloromethyltin

✍ Scribed by Christopher A. Bertelo; Christophe Duriez; Stéphane Girois; Bernard Jousseaume; Thierry Toupance

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
84 KB
Volume
17
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

The rate of disproportionation of trichloromethyltin in various solvents was studied by two methods, derivatization with sodium tetraethylborate and ^13^C NMR measurements, which gave similar results. The reaction followed second‐order kinetics and was more rapid in coordinating solvents than in uncoordinating ones. Moreover, it was catalyzed by nucleophiles, such as amines or alcohols, which is in favor of a nucleophile‐assisted electrophilic reaction. Copyright © 2003 John Wiley & Sons, Ltd.

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