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Studies on the constituents of marine opisthobranchia, IV. Two new polyhalogenated monoterpenes from the sea hareAplysia kurodai

✍ Scribed by Miyamoto, Tomofumi ;Higuchi, Ryuichi ;Marubayashi, Nobuhiro ;Komori, Tetsuya

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 281 KB
Volume: 1988
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.198819881215

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✦ Synopsis

A new cyclic moooterpene, aplysiateerpenoid A (I), and a new acyclic monoterpene, apl ysiateqxnoid B (2), have been isolated from the marine mollusk, Aplysiu kurodai (Aplysiidae), and their stmcturcs wcre dctermined by chemical, spectral. and X-ray structural investigations.

As described in the preceding paper') two new isoprenoids, aplykurodin A and B, were isolated from the body of the sea hare, Aplysia kurodai, and characterized. In continuation of the study, the terpenoid constituents of the body were surveyed, and we now wish to report the isolation and structure of the two less polar compounds, aplysiaterpenoid A (1) and B (2), and their characterization as new halogenated monoterpenes. Scheme 1 A p l y s i a k u r o d a a (13 bodies, 10 kg) -, Body wall Midgut gland MeOH extract 192.0 gi

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