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Studies on the asymmetric cycloaddition of 2-azaallyl anions with alkenes

✍ Scribed by William H Pearson; Erland P Stevens; Aaron Aponick

Book ID: 104231588
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 113 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01539-8

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The preparation of a variety of highly substituted pyrrolidines was achieved by solid-phase synthesis through the [2rts + 4~s] cycloaddition of 2-azaallyl anions with alkenes. Resin-bound aldehydes 2 were condensed with ct-arnino stannanes 3 to afford (2-azaallyl)stannanes 4. Transmetalation of 4 wi

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