Studies on the alkaloids of loti embryo. (1). Structure of isoliensinine.
✍ Scribed by M. Tomita; H. Furukawa; T.H. Yang; T.J. Lin
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 191 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
In 1962, Pan Pei-chuan p& al. (1) reported the isolation of liensinine from Chinese drug "Lien Tze H&no, embryo loti, ( embryo of the seed of Nelumbo nucifera GAERTN., Fam. Nymphaeaceae ) and its structure was shown to be I (2) , based on the result of its Hofmann degradation and permenganate oxidation reactions. Recently we isolated a new phenolic bisbenzylisoquinoline alkaloid from Formosan "Lien Tze PIsine, for which we proposed the name isollenslnine. Isoliensinine ( II 1 is a colorless oily base, which showed [d]f+49.3*(acetone), @JE9 -43.3'(CHC13), I.R.tizg13 3500 cm-f (OH), U.v.X ;?%EtOB 286v(log& 4.041, n.m.r. signals(3) 2637
📜 SIMILAR VOLUMES
TWO alkaloids, Chysin A (I) and Chysin B (II), have been isolated from Chysis bractescens Lindl. Chysin A (n M.wt. 169xx. z5 1,4763, bD]+63.5'.
The Bmzilian tree Aspidosperma dasycarpon 3 A. DC. has already yielded a number of interesting congeners4 (II-VI) of I u eine (I$ as well as the novel alkaloid apparicine (Vll).6 We should now like to record the isolation of still another alkaloid, "aspidodasycarpine, " to which we attribute structu