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Studies on sulfoxide rearrangements: regioselective synthesis of 3-(aryloxyacetyl)-2,3-dihydrothieno[3,2-c][1]benzopyran-4-ones

✍ Scribed by K.C Majumdar; S.K Ghosh


Book ID
104250624
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
131 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


Hitherto unreported 3-(aryloxyacetyl)-2,3-dihydrothieno[3,2-c][1] benzopyran-4-ones 5a-f were synthesised in 70-75% yields by the application of the sulfoxide rearrangement of 4-(4-aryloxybut-2-ynylthio)[1]benzopyran-2-ones 4a-f. The substrates 4a-f were synthesised by phase-transfer-catalysed alkylation of previously unreported 4-mercaptocoumarin.


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ChemInform Abstract: Studies on Sulfoxid
✍ K. C. Majumdar; S. K. Ghosh πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

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