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Studies on some bulky triorganotin complexes of germatranyl-substituted carboxylic acids

✍ Scribed by Xueqing Song; Qinglan Xie; Xiaoniu Fang

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 117 KB
Volume: 13
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.10039

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✦ Synopsis

Abstract

Eleven tris(2‐methyl‐2‐phenylpropyl)tin as well as four methyl bis[(phenyldimethylsilyl)methyl]tin β‐germatranylpropionates have been synthesized, and their structures were characterized by elemental analyses, IR, multinuclear (^1^H, ^13^C, ^119^Sn) NMR, Mössbauer, and MS spectroscopies. All the spectroscopic studies suggest a tetrahedral geometry for the bulky triorganotin carboxylates. The preliminary bioassays have shown that most of the compounds have good acaricidal activity. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:592–598, 2002; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10039

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