✦ LIBER ✦
Studies on reductive alkylation: Synthesis of Wieland-Miescher ketone analogues bearing an oxygenated angular substituent
✍ Scribed by L.N. Mander; R.J. Hamilton
- Book ID
- 104234412
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 270 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Wieland-Miescher analogues 2a and 2b have been prepared in good yield by a sequence utilising reductive alkylatTon of The dihydro aromatic ester enolate Id, which functions as a synthetic equivalent of the dioxo ester 5 anion; these analogues are envisaged as intermediates in a projected synthesis-of bruceantin.