Studies on reactions of ozone with alkenes
โ Scribed by Agnieszka Protczak; Jerzy Trzeszczynski
- Publisher
- Springer-Verlag
- Year
- 2002
- Tongue
- English
- Weight
- 496 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0944-1344
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Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p = 1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and
The gas-phase reaction of ozone with eight alkenes including six I ,I-disubstituted alkenes has been investigated at ambient T (285-298 K) and p = 1 atrn. of air. The reaction rate constants are, in units of lo-" cm3 molecule-' s ~' . 9 50 5 1.23 for 3-methyl-I-butene. 13 I ? I 8 for 2-methyl-I-pent