Studies on platinum(II) and palladium(II) complexes of someN,N′-disubstituted thiourea derivatives
✍ Scribed by Talal A. K. Al-Allaf; Ihsan A. Mustafa; Sa'ad E. Al-Mukhtar
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 474 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0340-4285
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✦ Synopsis
A series of new Pt n and Pd I1 complexes of N,N'-disubstituted thiourea derivatives of general formulae [MLCI2]2, [MLzCI;] and [ML4]CI 2 have been prepared and characterised by physicochemical and spectroscopic methods. The reaction of these ligands with [M(DMSO)2CI2], M = Pt, cis-or Pd, trans-, in CHC13 and EtOH at ambient temperature or under reflux, is described.
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2.2.3 Reactions of Pro-Gly-Ala-His and His-Pro-Gly-Ala-His with [Pd(en)(D 2 O) 2 ] 2 + and cis-[Pt(NH 3 )(D 2 O) 2 ] 2 + .
## Abstract Stepwise syntheses of monometallic palladium(II) and bimetallic palladium(II)/platinum(II) complexes were carried out in order to measure the metallophilicity of potential tetradentate bis(alkylthio)ylidenemalonato ligands. The reaction of [Pd](SO~4~) ([Pd] = (Me~4~en)Pd; Me~4~en = __N_