Studies on Phosphorus Phthalocyanines and Triazatetrabenzcorroles

✍ Scribed by Junzhong Li; Lakshminarayanapuram R. Subramanian; Michael Hanack

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 178 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-193X
• DOI: 10.1002/(sici)1099-0690(199812)1998:12<2759::aid-ejoc2759>3.0.co;2-9

✦ Synopsis

The previously reported reaction of phthalocyanines [H 2 (pc)] 5-8. The corresponding dihydroxyphosphorus(V) phthalocyanine hydroxides 9-12 have also been synthesized for the with PBr 3 , which was claimed to give a phosphorus(III) phthalocyanine "(PcP III )", has been reinvestigated in detail first time by insertion of phosphorus(V) into phthalocyanines and have been characterized in detail. The different with both unsubstituted and alkyl-substituted phthalocyanines, 1-4. The products exhibit unusual electronic and reactivities of PBr 3 and POX 3 (X = Cl, Br) toward phthalocyanines are discussed. mass spectra compared to normal phthalocyanines and have been identified as oxophosphorus(V) triazatetrabenzcorroles