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Studies on peroxidation of arachidonic acid in different liposomes below and above phase transition temperature

✍ Scribed by Giovanna Cervato; Paola Viani; Massimo Masserini; Clara Di Iorio; Benvenuto Cestaro


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
307 KB
Volume
49
Category
Article
ISSN
0009-3084

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✦ Synopsis


The mechanism of Fe-induced peroxidation of arachidonic acid (AA) in small unilameilar vesicles (SUV) of dipalmitoyl-phosphatidylehoUne (DPPC) and dipalmitoylphosphatidylethanolamine (DPPE) was studied below and above gel to liquid-crystalline phase transition temperature (T,). In both liposomes the AA peroxidation resulted higher in the temperature range below T, but the extent of malonyldialdehyde (MDA) formation was dramatically lower in DPPE vesicles when compared with corresponding DPPC liposomes. A possible explanation for this is discussed.