It is well known that 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide, 1, is a most effective thiation reagent for ketones." carboxamides ,'-' esters,' 1 ' ' -S-subst itu ted thloesters,e enaminones , I ' lactams," and Yand 6-lactones." In our attempts to transform @-propiolacton
✦ LIBER ✦
Studies on organophosphorus compounds—XL: Reactions of ketones with 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide
✍ Scribed by S. Scheibye; R. Shabana; S.-O. Lawesson; C. Rømming
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 701 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract 2,4‐Bis‐(4‐methoxyphenyl)‐1,3,2,4‐dithiadiphosphetane‐2,4‐disulfide (Lawesson's reagent) (**1**) reacted with 2‐hydrazino‐3‐methyl‐quinoxaline (**2**) to give [1,2,4,3]‐triazaphospholo[4,5‐__a__]quinoxaline derivative **3**. The Mannich reaction using different amines on compound **3**
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