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Studies on organophosphorus compounds XX. syntheses of thioketones

✍ Scribed by B. S. Pedersen; S. Scheibye; N. H. Nilsson; S.-O. Lawesson


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
273 KB
Volume
87
Category
Article
ISSN
0037-9646

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A series of dialkyl 1-(N-substituted amino)-2,2,2-trifluoroethylphosphonates was synthesized by Arbuzovtype reactions involving an N-substituted trifluoromethylimidoyl chloride and the appropriate trialkyl phosphite. The resulting C‫ב‬N bond was successfully hydrogenated by NaBH 4 CN treatment. The