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Studies on organophosphorous compounds: IX. C-Phosphorylation of compounds bearing an active methylene group

✍ Scribed by Yuan Cheng-Ye; Ding Yi-Xiang; Long Hai-Yan; Li Shu-Sen


Book ID
112058494
Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
628 KB
Volume
1
Category
Article
ISSN
0256-7660

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Study on the Pd/C-Catalyzed (Retro-)Mich
✍ Nicolai I. Nikishkin; Jurriaan Huskens; Willem Verboom πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 323 KB

## Abstract Palladium on carbon (10 % Pd/C) efficiently catalyzes the (retro‐)Michael addition of activated methylene compounds **2a**–**d**, such as malononitrile (**2b**), to mono‐ and doubly activated styrenes **1a**–**h** to give the adducts **3a**–**l**. The scope and limitations are described