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Studies on monocyclopentadienyl titanium(IV) dithiocarbamato complexes

✍ Scribed by O. P. Pandey; S. K. Sengupta; S. C. Tripathi

Publisher: Springer Vienna
Year: 1985
Tongue: English
Weight: 293 KB
Volume: 116
Category: Article
ISSN: 0026-9247
DOI: 10.1007/bf00798364

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## Abstract New monocyclopentadienyl species of Ta^V^, [Cp\*TaL~3~(XR)] (L = Cl, Me, X = O, S) bearing 4,6‐dimethyl‐2‐pyrimidinethiolate (SR = SC~6~H~7~N~2~) or 3‐cyano‐4,6‐dimethyloxypyridine (OR = OC~8~H~7~N~2~) ligands were prepared, namely [Cp\*TaCl~3~(SC~6~H~7~N~2~)] (1), [Cp\*TaCl~3~(OC~8~H~7