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Studies on Indian Ocean Manganese Nodules: 9. Catalytic Oxidation of Thiols to Disulphides by Central Indian Ocean Ferromanganese Nodules

✍ Scribed by K.M. Parida; A. Samal; N.N. Das

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 102 KB
Volume: 197
Category: Article
ISSN: 0021-9797
DOI: 10.1006/jcis.1997.5260

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✦ Synopsis

extensively studied and the results are well documented in The oxidation of thiols to corresponding disulfides by Indian the literature ( 16). However, their oxidizing ability and cata-Ocean ferromanganese nodules has been studied under varying lytic activity for organic reactions have been sparsely studied experimental conditions. More than 90% conversion of thiols (2.5 (17,18). With these in view, the oxidation of thiols to 1 10 03 mol) was achieved at 35ЊC using 0.1 g nodules. The oxides disulfides by different Indian Ocean manganese nodules has of Mn, Fe, Ca, Mg, and Al and surface oxygen in the nodules are been studied and the results are reported.

most likely responsible for the oxidation of thiols. Under identical conditions the oxidative conversion of thiols decreases in the order 1-dodecanethiol õ 1-hexanethiol õ 1,4-butanedithiol õ a-tolu-EXPERIMENTAL enethiol.

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