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Studies on formic acid-catalyzed dimerization of isorhapontigenin and of resveratrol to tetralins

✍ Scribed by Xiao-Mei Li; Kai-Sheng Huang; Mao Lin; Li-Xin Zhou

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
289 KB
Volume
59
Category
Article
ISSN
0040-4020

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The mechanism of the double proton transfer in formic acid dimer has been studied by the CNDO/2 .method in a quasi-dynamic way taking into account some zero-point vibrational deformations of the heavy atom skeleton. Substantial lowering of the potential barrier for the coupled motion of two protons