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Studies on fluoroalkylation and fluoroalkoxylation: 8. Palladium(0)-catalyzed addition reaction of fluoroalkyl iodides with alkynes

โœ Scribed by Qing-Yun Chen; Zhen-Yu Yang


Book ID
112058663
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
335 KB
Volume
4
Category
Article
ISSN
0256-7660

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โœ Shengming Ma; Xiyan Lu ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 423 KB

Abetract: Samarium diiodide was found to be an effective initiator in the addition reaction of fluoroalkyl iodides to alkynes. A single electrontransfer radical chain mechanism was proposed for the reaction based on ESR studies and other experimental results. Samarium diiodide, a strong single-elec