✦ LIBER ✦
Studies on epoxides. Part II. Abnormal lithium aluminium hydride reduction of cis 3,4-epoxy-5-hydroxycholestanes
✍ Scribed by E. Glotter; S. Greenfield; D. Lavie
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 147 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
As part of our studies on a-substituted epoxides we have prepared 3a. 4u-epoxy-5ahydroxycholeetane (I) and 38,48-epoxy-58-hydroxycholestane (II). Hydrasine hydrate treatment of 4a. 5a-epoxycholestan-3-one (III) gave the allylic alcohol (IV)*, m.p.