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Studies of the stereochemistry and mechanism of the ene reaction using specifically deuterated pinenes

✍ Scribed by Garsky, Victor; Koster, David F.; Arnold, Richard T.


Book ID
127385374
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
491 KB
Volume
96
Category
Article
ISSN
0002-7863

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The reaction catalyzed by bacterial GDP-mannose dehydratase (E.C. 4.2.1.47), the conversion of GDP-D-mannose to GDP-4-keto-6-deoxymannose (GDP-6-deoxy-D-lyxo-hexos-4-ulose), was studied with (6R)- and (6S)-GDP-D-[4-2H1,6-3H]mannose. Conversion of these stereospecifically labeled substrates in the pr