Based on the defect models that the two tetragonal Cu 2+ centers in KTaO 3 are due to Cu 2+ ions at Ta 5+ sites associated, respectively, with one and two oxygen vacancies (V 0 ) along C 4 axis because of charge compensation, the spin-Hamiltonian parameters (g factors g // , g β₯ and hyperfine struct
β¦ LIBER β¦
Studies of the spin-Hamiltonian parameters and the defect structure for Cu2+ at the rhombic Be2+ site of beryl crystal
β Scribed by Wang Fang; Wen-Chen Zheng
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 125 KB
- Volume
- 404
- Category
- Article
- ISSN
- 0921-4526
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The complete high-order perturbation formulas based on a two-mechanism [i.e., crystal-field (CF) and charge-transfer (CT) mechanisms, the latter is neglected in the widely-used CF theory] model for the spin-Hamiltonian (SH) parameters (g factors g // , g ? and the hyperfine structure constants A //