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Studies of the kinetic, spectral and chemical properties of Fe(IV) pyrophosphate by pulse radiolysis

✍ Scribed by Jon D. Melton; Benon H.J. Bielski


Book ID
108046246
Publisher
Elsevier Science
Year
1990
Weight
710 KB
Volume
36
Category
Article
ISSN
1359-0197

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The transient absorption bands dm 3 9 Οͺ1 ( Ο­ 330, 525 nm, k Ο­ 5 Ο« 10 mol max f obtained on pulse radiolysis of N 2 O-saturated neutral aqueous solution of 4,4Ј-thiodi-Οͺ1 s ) phenol (TDPH) are due to the reaction of TDPH with ΠΈOH radicals and are assigned to phenoxyl radical formed on fast deprotonat